From vinyl pyranoses to carbasugars by an iron-catalyzed reaction complementary to classical Ferrier carbocyclization.
نویسندگان
چکیده
Starting from vinyl pyranoses an iron-catalyzed tandem isomerization-intramolecular aldolization reaction was developed to prepare cyclohexenone derivatives bearing substituents on the double bond, and it has been applied in a short synthesis of 4-epi-gabosines A and B, from d-glucose.
منابع مشابه
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ورودعنوان ژورنال:
- Chemical communications
دوره 31 شماره
صفحات -
تاریخ انتشار 2009